Why Choose Boron Doped DIAMOND Electrode Over Mixed Metal Oxide Electrode

A Comparison Between MMO and Boron Doped Diamond Electrodes

To explore the differences between boron doped diamond electrode and mixed metal oxide (MMO) electrode as the next-gen electrode material for multiple electorchemical applications, in aspects such as dimensional & chemical stability, electrochemical potential window, background current, electrchemical efficiency and organic oxidation.                                                                                                                                                                                                                                                                                                                                                                                                      Boron doped diamond (BDD) electrodes exhibit a spectrum of exceptional properties, distinguishing themselves as unparalleled in the realm of electrochemistry. Their standout features include an impressively expansive potential window, surpassing that of any other electrode material. Particularly noteworthy is their prowess in anodic potentials, setting a new standard for electrochemical exploration. Moreover, BDD electrodes boast remarkably low background and capacitive currents, underscoring their efficiency in various applications. Compared to conventional MMO/DSA electrodes, they showcase reduced fouling, ensuring prolonged and consistent performance, making them a top choice for industries seeking reliability and precision.

bdd electrodes
Boron Doped Diamond (BDD) Electrode

Chemical Stability                                                                                                                                                                                                                                                                                                                    One of the standout characteristics of boron doped diamond electrodes is their exceptional chemical stability. It’s virtually impervious to corrosion, which makes it an ideal choice for applications where exposure to harsh chemicals is a constant concern. Boron-doped diamond is almost entirely chemically inert, meaning it won’t react with most chemicals, which makes boron doped diamond electrode an ideal anode material for applications involving strong acids, bases, and aggressive compounds, making these electrodes the prime choice in wastewater treatment toward industries such as lithium battery production/recycling, gas & petroleum and pharmecutical.                                                                                                                                                                                                                                             MMO electrodes exhibit resistance to corrosion and can withstand various chemical environments. However, prolonged exposure to exceedingly aggressive conditions might cause a gradual decline in their performance. BDD electrodes triumph over MMO electrodes in terms of chemical stability, showcasing exceptional resistance to a broad spectrum of chemicals and thriving in even the harshest conditions. While MMO electrodes display good corrosion resistance, they may require more attention to uphold their longevity in extremely harsh environments.

 Remarkable Low Background Current                                                                                                                     
The reduced background current associated with diamond electrodes not only enhances sensitivity but also lowers detection limits, making it an ideal choice for cutting-edge research. This exceptional material has sparked considerable interest in the scientific community, thanks to its unique properties that enable groundbreaking research and experimentation.Boron-doped diamond electrodes perform better than conventional MMO electrodes under stronger current density and higher pH. 

Dimensional Stability                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  BDD electrodes exhibit an extraordinary level of dimensional stability, remaining virtually unaltered in physical structure even during prolonged use. BDD boasts a low coefficient of thermal expansion (CTE) close to zero, meaning it does not expand or contract significantly with changes in temperature. This property is invaluable in high-precision equipment and electronics, as it minimizes the risk of thermal stress-induced damage.This outstanding attribute is pivotal for applications requiring consistent and enduring electrode performance over extended periods.  MMO electrodes offer satisfactory dimensional stability, although not reaching the extraordinary level demonstrated by BDD electrodes. They are suitable for prolonged use but may require more frequent maintenance to ensure consistent performance.

Electrochemical Potential Window

BDD electrodes have the largest electrochemical potential window in aqueous solutions compared to traditional electrodes like gold, platinum etc,. Traditionally, electrode surfaces like gold (Au) and platinum (Pt) limited the analysis of reactions to certain potential ranges. However Boron-doped diamond (BDD) electrodes are a game-changer in electrochemical analysis experiment, offering an expansive potential window in aqueous solutions and impressively low background currents. Testing results indicated reactions occurring in potential ranges spanning from approximately -0.4V to -1.3V and about +1.7V to 2.6V.

Oxygen evolution overpotential comparison between conventional electrode and bdd electrode

Boron doped diamond (BDD) electrode is one of the non-active electrode materials with highest oxygen evolution overpotential thanks to the unique SP3 structure.  Boron doped diamond electrode requires larger potential to initiate the oxygen evolution reaction, making it ideal for electrochemical applications requires high rate of oxidation/redox reaction but yet no side reactions, the OER advantages of this electrode material are accomplished via its exceptional chemical and dimensional stability and wider potential window.

Oxygen evolution overpotential (V vs. SHE) comparison between conventional electrode materials and boron doped diamond electrode demonstrated that Titainium/Boron doped diamond electrode performed much higher oxygen evolution overpotential and oxidation power than MMO electrode and conventional electrode material.

Oxidizing potential for conventional oxidizing agents and ranking of hydroxyl radicals in oxidation capability, mainly generated from the surface of bdd electrode

Hydroxyl radicals can be electrochemically generated on the surface of boron doped diamond electrode once electric current and potential applied, check electrolysis process via boron doped diamond electrodes here, the electrolysis processes dismantling H2O to generate hydrogen atom and oxygen, combined to form hydroxyl radicals. Hydroxyl radicals are the second most active oxidizing agents. Hydroxyl radicals react rapidly with many organic compounds through series of interaction. They performed strong chemical deterioration and released constant organic molecules mineralization, breaking these compounds into carbon dioxide, water, and etc.

Explore More Details About Electrochemical Wastewater Treatment via Boron Doped Diamond Electrode Electrolysis

Wastewater Treatment Efficiency Comparison Between BDD Electrode And MMO Electrodes

Under identical conditions, BDD electrode exhibits significantly superior efficiency in refractory organic pollutants degradation, and lower energy consumption during the electrochemical oxidation remediation of real effluents, compared to traditional anode materials such as Pt Iridium Oxide, Titanium and etc.  Boron-doped diamond electrodes not only offer a significantly higher electrochemical efficiency compared to conventional materials like iridium oxide, but also have the lowest energy consumption at 4.3 × 103 kWh KG-COD −1 according to tests conducted by Evoaeo research team.This means they require less energy to drive electrochemical processes, resulting in reduced operational costs. BDD electrodes excel in degradation of various pollutants especially organic compounds, making them a cost-effective choice for various wastewater treatment applications.                                                                                                                                            

The charts below demonstrate comparison of BDD electrode and specific traditional electode over color removal efficiency (left), COD removal efficiency, and removal percentage, and then energy consumptions: 

BDD electrode vs Pt electrode
BDD electrode vs MMO electrode
BDD electrode vs PbO2 electrode
comparison between boron doped diamond electrode Pbo2 electrode

Electrochemical Treatment Application of BDD Electrodes: Products,Case Studies & Solutions

As one of the suppliers of boron doped diamond electrode and manufacturer of advanced electro oxidation wastewater treatment equipments, Evoaeo team conducted component designs, treatability testing, close projects monitoring to address industrial wastewater treatment.                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        With deep understanding of water treatment and electro-oxidation, we developed electrolytic cells, electrolyzers, electro oxidation equipment for organic wastewater treatment, and supply oxidation treatment equipments at commercial scale to efficient and environmentally responsible practices in industrial wastewater treatment based on BDD electrode, check our product lines, previous projects, and what is more, industrial wastewater solutions.
Electro oxidation electrode materials, such as BDD electrodes, MMO anodes and electro oxiation water treatment products from electro oxidation trial modules, portable testing kit, up to systems.
Explore case studies and water treatment projects conducted by Evoaeo team via advanced electro oxidation treatment technology, and how electro oxidation combined with other treatment methods.
Advanced electro oxidation water treatment technology applications and implement in different niches , and explore how Evoaeo bring advanced electro oxidation solutions to remove organic polluants.

Boron Doped Diamond Solutions for Treatment of Organic Pollutants in Water

Boron doped diamond electrodes excel in their ability to fully oxidize organic pollutants, ensuring the comprehensive elimination of refractory organic contaminants. This prowess stems from their exceptional electrochemical activity, which enables them to break down complex pollutants into harmless byproducts. Boron doped diamond electrodes provide a remarkable advantage in that they offer a precise current response directly correlated with the Chemical Oxygen Demand (COD) values of the sample solution. This feature is invaluable for analytical purposes, as it allows for accurate and real-time monitoring of pollutant levels. Researchers and environmental professionals can rely on this feature for robust data collection and analysis. BDD electrodes demonstrate higher efficiency in removing a broader spectrum of organic pollutants, including complex and persistent compounds, making them versatile in various industrial settings. In contrast, MMO electrodes are more effective for specific, known pollutants with less complexity.

Phenols removal with boron doped diamond bdd electrode
Boron doped diamond electrode degrades phenols and their derivatives, including phenol itself, primarily originate from petrochemical enterprises.
active pharmaceutical ingredient degradation via boron doped diamond bdd electrode
Pharmaceutical intermediates, such as 17β-estradiol, are primarily sourced from pharmaceutical and chemical enterprises.
Dyes and pigments removal with boron doped diamond bdd electrode
Dyes and pigments, such as methyl orange, come mainly from printing and dyeing factories

Evoaeo’s Electro Oxidation Water Treatment Solution, Practical Implements About Electrochemical Treatment for Organic Wastewater

Thanks to its exceptional chemical stability and durability, magnificent electrochemical potential window, remarkable background current and superb electrochemical efficiency, Boron doped diamond electrodes(BDD electrodes) can withstand harsh chemical environments, allowing for the precise decomposition and synthesis of various refractory compounds.                                                                                                                                                                                                                                                                                                                                                                     This has far-reaching implications in industries such as pharmaceuticals, chemicals, petrochemicals, lithium-ion battery production & recycling, and materials science, where controlled reactions and transformations are crucial. Leveraging its unique electrochemical properties and capability, boron-doped diamond electrode serves as an exceptional choice for electrodes, particularly in electrochemical water treatment systems.                                                                                                                                                                                                                                                                                                                                                                                                                                                                                       Boron-doped diamond (BDD) electrodes can efficiently remove organic contaminants, pathogens, and impurities from water, making it a pivotal player in enhancing water quality and safety. Evoaeo dedicated to research and development of Boron-doped diamond electrode and wastewater treatment systems based on advanced electrochemical oxidation technology.

We offer advanced electrochemical oxidation wastewater treatment solutions to minimization of refractory organic pollutants found in wastewater from various industries.

pharmaceutical wastewater treatment

Pharmaceutical & Bio

Eliminating APIs and challenging pollutants from wastewater for pharmaceutical companies and the biopharma and biotech sectors.

petroleum wastewater treatment

Petrochemical

Innovative tertiary treatment solution tailored to the challenge of addressing recalcitrant and hazardous organic compounds, such as BTEX and phenols.

Chemical

Empowers specialty chemical manufacturers to degrading biocides, active ingredients, obstinate COD, and micropollutants.

agrichemical wastewater treatment

And More To Come

Evoaeo will present many more solutions to tackle challenges from more industries and sectors, especially industrial effluents with recalcitrant organic compounds

Explore BDD Electrode With Evoaeo

Unleash the full potential of Boron-doped diamond electrodes in your research endeavors with our dedicated technical support team.

Elevate your experiments with our unmatched customization and stellar service.
Reach out today and let us transform your boron doped diamond electrode needs into bespoke solutions for unparalleled success.
Employing optioneering techniques to pinpoint the most suitable solution.

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